(o-Benzoquinone diimine-N,N')dichlorobis(triphenylphosphine-P)ruthenium(II) 1.33-methanol 0.33-dichloromethane solvate

Diego Venegas-Yazigi; Hameed Mirza; A. B. P. Lever; Alan J. Lough; Juan Costamagna; Andrés Vega; Ramón Latorre

doi:10.1107/S0108270100006144

(o-Benzoquinone diimine-N,N')dichlorobis(triphenylphosphine-P)ruthenium(II) 1.33-methanol 0.33-dichloromethane solvate

Acta Crystallogr C. 2000 Jun 1;56(Pt 6):E245-E246. doi: 10.1107/S0108270100006144. Epub 2000 Jun 1.

Authors

Diego Venegas-Yazigi¹, Hameed Mirza, A. B. P. Lever, Alan J. Lough, Juan Costamagna, Andrés Vega, Ramón Latorre

Affiliation

¹ Departamento de Química, Facultad de Ciencias, Universidad de Chile, Casilla 653, Santiago, Chile.

PMID: 15263111
DOI: 10.1107/S0108270100006144

Abstract

The Ru atom in the title compound, [RuCl(2){P(C(6)H(5))(3)}(2){C(6)H(4)(NH)(2)}].1.33CH(3)OH.0.33CH(2)Cl(2), shows a six-coordinate octahedral geometry, with a trans arrangement of the triphenylphosphine groups. One and a half molecules of complex, two molecules of methanol and a half molecule of dichloromethane form the asymmetric unit, with crystallographic twofold rotation symmetry for the complex molecule in a special position.