Dichloro(methanol-kappaO)[(methoxy)tris(1-methyl-1H-imidazol-2-yl)methane-kappa2N3]iron(II) (ca 153 K)

Michael P Batten; Allan J Canty; Kingsley J Cavell; Thomas Rüther; Brian W Skelton; Allan H White

doi:10.1107/S010827010401087X

Dichloro(methanol-kappaO)[(methoxy)tris(1-methyl-1H-imidazol-2-yl)methane-kappa2N3]iron(II) (ca 153 K)

Acta Crystallogr C. 2004 Jul;60(Pt 7):m314-5. doi: 10.1107/S010827010401087X. Epub 2004 Jun 22.

Authors

Michael P Batten¹, Allan J Canty, Kingsley J Cavell, Thomas Rüther, Brian W Skelton, Allan H White

Affiliation

¹ Department of Chemistry, University of Tasmania, Hobart, 7001, Australia.

PMID: 15237145
DOI: 10.1107/S010827010401087X

Abstract

In the quasi-trigonal-bipyramidal environment of the five-coordinate Fe(II) atom in the title compound, [FeCl2(C14H18N6O)(CH4O)], the methanol and one of the N-atom donors of the potentially tridentate ligand are disposed axially: Fe-N(axial) is 2.149 (2) A, Fe-N(equatorial) is 2.108 (2) A and N-Fe-O is 174.14 (7) degrees.