Cis-dinitrito(1,4,8,11-tetraazacyclotetradecane-kappa4N)chromium(III) nitrite

Jong-Ha Choi; In-Gyung Oh; Woo-Taik Lim; Ki-Min Park

doi:10.1107/S0108270104007656

Cis-dinitrito(1,4,8,11-tetraazacyclotetradecane-kappa4N)chromium(III) nitrite

Acta Crystallogr C. 2004 Jun;60(Pt 6):m238-40. doi: 10.1107/S0108270104007656. Epub 2004 May 11.

Authors

Jong-Ha Choi¹, In-Gyung Oh, Woo-Taik Lim, Ki-Min Park

Affiliation

¹ Department of Chemistry, Andong National University, Andong 760-749, South Korea. jhchoi@andong.ac.kr

PMID: 15178835
DOI: 10.1107/S0108270104007656

Abstract

In the title compound, [Cr(ONO)(2)(cyclam)]NO(2) (cyclam is 1,4,8,11-tetraazacyclotetradecane, C(10)H(24)N(2)), the complex cation is located on a twofold symmetry axis. The central Cr atom has a distorted octahedral coordination, involving two Cr-O bonds, with the monodentate nitrite O atoms adopting a cis configuration, and four Cr-N bonds. The mean Cr-N and Cr-O distances are 2.0895 (14) and 1.9698 (14) A.