Dynamic helicity inversion by achiral anion stimulus in synthetic labile cobalt(II) complex

Hiroyuki Miyake; Kana Yoshida; Hideki Sugimoto; Hiroshi Tsukube

doi:10.1021/ja049130o

Dynamic helicity inversion by achiral anion stimulus in synthetic labile cobalt(II) complex

J Am Chem Soc. 2004 Jun 2;126(21):6524-5. doi: 10.1021/ja049130o.

Authors

Hiroyuki Miyake¹, Kana Yoshida, Hideki Sugimoto, Hiroshi Tsukube

Affiliation

¹ Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan. miyake@sci.osaka-cu.ac.jp

PMID: 15161259
DOI: 10.1021/ja049130o

Abstract

The helical chirality of a Co(II) complex with a chiral tetradentate ligand is completely inverted from Lambda to Delta by the addition of achiral NO3- anion as an external stimulus.