Bis(acetone-kappaO)bis(N,N'-dimethylethylenediamine-kappa(2)N,N')copper(II) diperchlorate

Takashiro Akitsu; Yasuaki Einaga

doi:10.1107/S010827010400349X

Bis(acetone-kappaO)bis(N,N'-dimethylethylenediamine-kappa(2)N,N')copper(II) diperchlorate

Acta Crystallogr C. 2004 Apr;60(Pt 4):m162-4. doi: 10.1107/S010827010400349X. Epub 2004 Mar 11.

Authors

Takashiro Akitsu¹, Yasuaki Einaga

Affiliation

¹ Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, Yokohama 223-8522, Japan.

PMID: 15071204
DOI: 10.1107/S010827010400349X

Abstract

The title compound, [Cu(C(4)H(12)N(2))(2)(C(3)H(6)O)(2)](ClO(4))(2), is the first structurally characterized Cu(II) complex having acetone as axial ligands. The complex adopts an elongated octahedral trans-[CuN(4)O(2)] coordination geometry, with the Cu atom having 222 site symmetry. The axial Cu-O(acetone) and in-plane Cu-N bond lengths are 2.507 (5) and 2.041 (3) A, respectively.