Unification of the hole transport in polymeric field-effect transistors and light-emitting diodes

Phys Rev Lett. 2003 Nov 21;91(21):216601. doi: 10.1103/PhysRevLett.91.216601. Epub 2003 Nov 19.

Abstract

A systematic study of the hole mobility in hole-only diodes and field-effect transistors based on poly(2-methoxy-5-(3('),7(')-dimethyloctyloxy)-p-phenylene vinylene) and on amorphous poly(3-hexyl thiophene) has been performed as a function of temperature and applied bias. The experimental hole mobilities extracted from both types of devices, although based on a single polymeric semiconductor, can differ by 3 orders of magnitude. We demonstrate that this apparent discrepancy originates from the strong dependence of the hole mobility on the charge carrier density in disordered semiconducting polymers.