Direct carbamoylation of alkenyl halides

Org Lett. 2003 Dec 25;5(26):4947-9. doi: 10.1021/ol030110l.

Abstract

Alkenyl chlorides and bromides are converted into tertiary enamides by treatment with a carbamoylsilane in toluene at 110 degrees C in the presence of phosphine-palladium(0) catalysts. [reaction: see text]