The first nonempirical circular dichroism determination of the absolute configuration of N-phthalimidosulfoximines based on exciton coupling mechanism and a correlation with the absolute configuration of chiral sulfoxides

Jacek Gawroński; Jakub Grajewski; Józef Drabowicz; Marian Mikołajczyk

doi:10.1021/jo030188f

The first nonempirical circular dichroism determination of the absolute configuration of N-phthalimidosulfoximines based on exciton coupling mechanism and a correlation with the absolute configuration of chiral sulfoxides

J Org Chem. 2003 Dec 12;68(25):9821-2. doi: 10.1021/jo030188f.

Authors

Jacek Gawroński¹, Jakub Grajewski, Józef Drabowicz, Marian Mikołajczyk

Affiliation

¹ Department of Chemistry, A. Mickiewicz University, 60-780 Poznań, Poland.

PMID: 14656115
DOI: 10.1021/jo030188f

Abstract

A simple nonempirical method for the assignment of absolute configuration of N-phthalimidosulfoximines and related S-chiral sulfoxides, based on exciton-coupled circular dichroism, is presented.