A novel vehicle emissions remote sensing system (VERSS) for the on-road measurement of fuel-based particulate matter (PM) emission factors is described. This system utilizes two complementary PM channels using an ultraviolet Lidar and transmissometer for the measurement of PM mass column content behind a passing vehicle. Ratioing the PM mass column content with the carbon mass column content, simultaneously measured with infrared absorption, yields the fuel-based PM mass emission factor. The transmissometer directly yields PM extinction coefficients without calibration, while the Lidar measurement of PM backscatter coefficients is calibrated through laboratory measurements of gases with well-known backscatter coefficients. The PM mass column content is calculated from these extinction and backscatter coefficients with the help of mass backscatter and extinction efficiencies obtained from theoretical calculations. This novel VERSS has been used extensively in a major air quality study, and example data are presented.