Aminobromination of unsaturated phosphonates

Xin Qi; Sang-Hyeup Lee; Ji Young Kwon; Youngmee Kim; Sung-Jin Kim; Yoon-Sik Lee; Juyoung Yoon

doi:10.1021/jo034535x

Aminobromination of unsaturated phosphonates

J Org Chem. 2003 Nov 14;68(23):9140-3. doi: 10.1021/jo034535x.

Authors

Xin Qi¹, Sang-Hyeup Lee, Ji Young Kwon, Youngmee Kim, Sung-Jin Kim, Yoon-Sik Lee, Juyoung Yoon

Affiliation

¹ School of Chemical Engineering, Dalian University of Technology, Dalian 116012, People's Republic of China.

PMID: 14604398
DOI: 10.1021/jo034535x

Abstract

Unexpected syn beta-amino-alpha-bromination of unsaturated phosphonates was observed under typical Sharpless AA reaction conditions with excess N-bromoacetamide.