Advances in the synthesis of inorganic nanotubes and fullerene-like nanoparticles

Angew Chem Int Ed Engl. 2003 Nov 3;42(42):5124-32. doi: 10.1002/anie.200301651.

Abstract

In analogy to graphite, nanoparticles of inorganic compounds with lamellar two-dimensional structure, such as MoS(2), are not stable against folding, and can adopt nanotubular and fullerene-like structures, nicknamed inorganic fullerenes or IF. Various applications for such nanomaterials were proposed. For instance, IF-WS(2) nanoparticles were shown to have beneficial effects as solid lubricants and as part of tribological surfaces. Further applications of IF for high-tensile-strength fibers, hydrogen storage, rechargeable batteries, catalysis, and in nanotechnology are being contemplated. This Minireview highlights some of the latest developments in the synthesis of inorganic nanotubes and fullerene-like structures. Some structural aspects and properties of IF, which are distinct from the bulk materials, are briefly discussed.