Abstract
[reaction: see text]. SmI2/H2O/amine provides selective cleavage of unsubstituted allyl ethers in good to excellent yields. This method is therefore useful in deprotection of alcohols and carbohydrates.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alcohols / chemistry*
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Allyl Compounds / chemistry*
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Amines / chemistry
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Carbohydrates / chemistry
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Catalysis
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Ethers / chemistry*
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Ethylamines / chemistry
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Iodides / chemistry*
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Molecular Structure
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Phenyl Ethers / chemistry
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Propylamines / chemistry
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Samarium / chemistry*
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Water / chemistry
Substances
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Alcohols
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Allyl Compounds
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Amines
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Carbohydrates
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Ethers
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Ethylamines
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Iodides
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Phenyl Ethers
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Propylamines
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Water
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phenyl allyl ether
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Samarium
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samarium diiodide
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2-propylamine
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triethylamine