[(Th2F5)(NC7H5O4)2(H2O)][NO3]: an actinide-organic open framework

Jong-Young Kim; Alexander J Norquist; Dermot O'Hare

doi:10.1021/ja036832p

[(Th2F5)(NC7H5O4)2(H2O)][NO3]: an actinide-organic open framework

J Am Chem Soc. 2003 Oct 22;125(42):12688-9. doi: 10.1021/ja036832p.

Authors

Jong-Young Kim¹, Alexander J Norquist, Dermot O'Hare

Affiliation

¹ Inorganic Chemistry Laboratory, South Parks Road, University of Oxford, Oxford, OX1 3QR, UK.

PMID: 14558799
DOI: 10.1021/ja036832p

Abstract

We believe [(Th2F5)(NC7H5O4)2(H2O)][NO3] is the first three-dimensionally connected, actinide-organic framework solid. The structure is composed of thorium oxyfluoride chains, each of which connected to pyridinedicarboxylate groups to give a 3D cross-linked network with cavities containing nitrate anions.