1 Laboratoire d'Electrochimie Organique et de Photochimie Rédox, UMR CNRS 5630, Institut de Chimie Moléculaire de Grenoble, FR CNRS 2607, Université Joseph Fourier, BP 53, 38041 Grenoble cedex 09, France.
Construction and characterization of structural and charge transport properties of electrostatically LbL self-assembled multilayers of gold nanoparticles and a viologen-based redox-active polyelectrolyte is reported.