Cyanide-bridged Fe(III)-Co(II) bis double zigzag chains with a slow relaxation of the magnetisation

Luminita Marilena Toma; Rodrigue Lescouëzec; Francesc Lloret; Miguel Julve; Jacqueline Vaissermann; Michel Verdaguer

doi:10.1039/b302182n

Cyanide-bridged Fe(III)-Co(II) bis double zigzag chains with a slow relaxation of the magnetisation

Chem Commun (Camb). 2003 Aug 7:(15):1850-1. doi: 10.1039/b302182n.

Authors

Luminita Marilena Toma¹, Rodrigue Lescouëzec, Francesc Lloret, Miguel Julve, Jacqueline Vaissermann, Michel Verdaguer

Affiliation

¹ Department de Química Inorgànica/Instituto de Ciencia Molecular, Facultat de Química de la Universitat de València, Avda. Dr. Moliner 50, 46100-Burjassot (València), Spain.

PMID: 12931998
DOI: 10.1039/b302182n

Abstract

Reaction of [Fe(III)(bipy)(CN)4]- with fully solvated M(II) cations [M = Co (1) and Mn (2)] produces the isostructural bis double zigzag chains [[Fe(III)(bipy)(CN)4]2M(II)(H2O)] x MeCN x (1/2)H2O; 1 exhibits intrachain ferromagnetic and interchain antiferromagnetic couplings, slow magnetic relaxation and hysteresis effects.