Conducting nanowires in insulating ceramics

Nat Mater. 2003 Jul;2(7):453-6. doi: 10.1038/nmat920.

Abstract

Low-dimensional structures, such as microclusters, quantum dots and one- or two-dimensional (1D or 2D) quantum wires, are of scientific and technological interest due to their unusual physical properties, which are quite different from those in the bulk. Here we present a successful method for fabricating conducting nanowire bundles inside an insulating ceramic single crystal by using unidirectional dislocations. A high density of dislocations (10(9) cm(-2)) was introduced by activating a primary slip system in sapphire (alpha-Al2O3 single crystal) using a two-stage deformation technique. Plate specimens cut out from the deformed sapphire were then annealed to straighten the dislocations. Finally, the plates on which metallic Ti was evaporated were heat-treated to diffuse Ti atoms inside sapphire. As a result of this process, Ti atoms segregated along the unidirectional dislocations within about 5 nm diameter, forming unidirectional Ti-enriched nanowires, which exhibit excellent electrical conductivity. This simple technique could potentially to be applied to any crystal, and may give special properties to commonly used materials.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aluminum Oxide
  • Ceramics / chemistry*
  • Electric Conductivity*
  • Electric Wiring
  • Microscopy, Electron
  • Nanotechnology*
  • Titanium

Substances

  • Titanium
  • Aluminum Oxide