Synthesis, structure and reductive dechlorination of the C-centred phosphorus(III) beta-diketiminate PCl(Ph)L [L = C[C(Me)NC6H3Pri2(-2),6][C(Me)NHC6H3Pri2(-2),6]]

Peter B Hitchcock; Michael F Lappert; Jacek E Nycz

doi:10.1039/b301294h

Synthesis, structure and reductive dechlorination of the C-centred phosphorus(III) beta-diketiminate PCl(Ph)L [L = C[C(Me)NC6H3Pri2(-2),6][C(Me)NHC6H3Pri2(-2),6]]

Chem Commun (Camb). 2003 May 21:(10):1142-3. doi: 10.1039/b301294h.

Authors

Peter B Hitchcock¹, Michael F Lappert, Jacek E Nycz

Affiliation

¹ Chemistry Laboratory, University of Sussex, Brighton, UK BN1 90J.

PMID: 12790088
DOI: 10.1039/b301294h

Abstract

Treatment of the beta-diketimine HL with successively LiBun and PCl2Ph gave the first C-centered monodentate beta-diketiminate PCl(Ph)L 1; with C8K 1 underwent reductive dechlorination yielding 2, a novel N-PIII-PIII-C=C heterocycle.