Abstract
[reaction: see text] The synthesis of (+)-strictifolione was achieved from 3-phenylproprionaldehyde by using enantioselective allyltitanations to control the stereogenic centers at C6, C4', and C6' and a cross-methathesis to control the configuration of the double bond at C1'-C2'.
MeSH terms
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Aldehydes
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Antifungal Agents / chemical synthesis*
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Cross-Linking Reagents
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Indicators and Reagents
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Magnetic Resonance Spectroscopy
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Pyrones / chemical synthesis*
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Stereoisomerism
Substances
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Aldehydes
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Antifungal Agents
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Cross-Linking Reagents
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Indicators and Reagents
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Pyrones
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strictifolione
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3-phenylpropanal