Synthesis of degraded cyanogenic glycosides from Sambucus nigra

Nat Prod Res. 2003 Jun;17(3):177-81. doi: 10.1080/1057563021000040772.

Abstract

Two natural cyanohydrins, isolated from Sambucus nigra, have been synthesised from mandelonitrile and penta-O-acetyl-beta-galactopyranose. The synthesis confirmed the stereochemistry of the compounds, which had been assigned on biogenetic grounds.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Glycosides / chemistry
  • Magnetic Resonance Spectroscopy
  • Molecular Conformation
  • Nitriles / chemical synthesis*
  • Sambucus nigra / chemistry*

Substances

  • Glycosides
  • Nitriles
  • cyanohydrin