[New photoreactive cleavable reagents with (trifluoromethyl)diazirine group]

M T Mchedlidze; N V Sumbatian; D A Bondar'; M V Taranenko; G A Korshunova

doi:10.1023/a:1023268617727

[New photoreactive cleavable reagents with (trifluoromethyl)diazirine group]

Bioorg Khim. 2003 Mar-Apr;29(2):200-7. doi: 10.1023/a:1023268617727.

[Article in Russian]

Authors

M T Mchedlidze¹, N V Sumbatian, D A Bondar', M V Taranenko, G A Korshunova

Affiliation

¹ Faculty of Chemistry, Moscow State University, Vorob'evy gory, Moscow, 119899 Russia. manana_m@imail.ru

PMID: 12708321
DOI: 10.1023/a:1023268617727

Abstract

Photoreactive cross-linking reagents that simultaneously contain a trifluoromethyldiazirine and an o-nitrobenzyl groups were synthesized for the first time. Photochemical properties of the reagents were studied, and the possibility of separate activation of the diazirine group and o-nitrobenzyl linker was shown.

Publication types

English Abstract

MeSH terms

Biochemistry / methods
Cross-Linking Reagents / chemical synthesis
Cross-Linking Reagents / chemistry*
Diazomethane / analogs & derivatives
Diazomethane / chemistry*
Nitrobenzenes / chemistry
Photochemistry / methods
Ultraviolet Rays

Substances

Cross-Linking Reagents
Nitrobenzenes
Diazomethane