Methyl 3,6-di-O-pivaloyl-alpha-D-mannopyranoside

Acta Crystallogr C. 2003 Apr;59(Pt 4):O184-6. doi: 10.1107/s010827010300324x. Epub 2003 Mar 11.

Abstract

The X-ray crystal structure analysis of the title compound, C(17)H(30)O(8), revealed a (4)C(1) conformation of the pyranosyl ring [Cremer-Pople puckering parameters of Q = 0.568 (2) A, theta = 5.1 (2) and phi = 218 (3) degrees ]. The structure shows no deviations from the geometric parameters of pyranoside carbohydrates. The hydroxyl groups participate in O-H.O hydrogen bonds, forming a two-dimensional pattern [O.O = 2.811 (3) and 2.995 (3) A].

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carbohydrate Conformation
  • Crystallography, X-Ray
  • Hydrogen Bonding
  • Mannose / analogs & derivatives
  • Mannose / chemistry*
  • Models, Molecular

Substances

  • methyl 3,6-di-O-pivaloyl-mannopyranoside
  • Mannose