Two-type polymeric chiral stationary phases (pCSPs) were prepared by surface grafting of chiral acryl-type monomers on a silica gel surface modified with 3-(trimethoxysilyl)propylmethacrylate. The prepared pCSPs were characterized by IR, Fr-Raman, scanning electron microscopy, and elemental analysis. In addition, two-type monomeric chiral stationary phases (mCSPs) were also prepared. The racemic analytes were separated using the prepared mCSPs and pCSPs. The separation factor (alpha) and capacity factor (k1) of the racemic analytes for the pCSP and mCSP were compared. The alpha and k1 values of the mCSP were higher than those of the pCSP.