Abstract
The atom-centred FeMo cofactor of nitrogenase most likely contains N, resting at the [NMoFe7]18+ redox level, inserted from N2, and subsequently restricting the modes of binding of substrate to the NFe6 core.
Publication types
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Binding Sites
-
Electrons
-
Models, Molecular
-
Molecular Structure
-
Molybdoferredoxin / chemistry*
-
Nitrogen / chemistry*
-
Nitrogenase / chemistry*
-
Oxidation-Reduction
Substances
-
Molybdoferredoxin
-
Nitrogenase
-
Nitrogen