Treatment of industrial oily wastewaters by wet oxidation

J Hazard Mater. 2003 Feb 28;97(1-3):257-65. doi: 10.1016/s0304-3894(02)00265-0.

Abstract

In the present work, the homogeneous wet oxidation (WO) of an oily wastewater (COD approximately 11,000 mg l(-1)), composed mainly of alcohols and phenolic compounds, was studied in a high-pressure agitated autoclave reactor in the temperature range of 180-260 degrees C and oxygen pressure 1 MPa. Temperature was found to have a significant impact on the oxidation of the contaminants in the wastewater. Among the compounds contained in the wastewater, ethylene glycol showed great resistance to wet oxidation. Temperatures above 240 degrees C were required for its effective degradation. Organic acids, mainly acetic acid, were the intermediate products of the wet oxidation process and their conversion to carbon dioxide was very slow. A generalised model based on a parallel reaction scheme was used to interpret the experimental data obtained. The activation energies obtained were in the range of 90-130 kJ mol(-1).

MeSH terms

  • Alcohols
  • Industrial Waste*
  • Oils*
  • Oxidation-Reduction
  • Oxygen
  • Phenols
  • Pressure
  • Temperature
  • Waste Disposal, Fluid*

Substances

  • Alcohols
  • Industrial Waste
  • Oils
  • Phenols
  • Oxygen