Synthesis of 2-silyl substituted phospharuthenocenes and an elaboration into the first phospharuthenocene-phosphine

Duncan Carmichael; François Mathey; Louis Ricard; Nicolas Seeboth

doi:10.1039/b208736g

Synthesis of 2-silyl substituted phospharuthenocenes and an elaboration into the first phospharuthenocene-phosphine

Chem Commun (Camb). 2002 Dec 21:(24):2976-7. doi: 10.1039/b208736g.

Authors

Duncan Carmichael¹, François Mathey, Louis Ricard, Nicolas Seeboth

Affiliation

¹ Laboratoire Hétéroéléments et Coordination, UMR CNRS 7653, DCPH Ecole Polytechnique, 91128 Palaiseau, France. Duncanc@mars.polytechnique.fr

PMID: 12536774
DOI: 10.1039/b208736g

Abstract

A [1,5] shift protocol transiently hindering the 2-position of phospholide anions provides an access to sterically unencumbered phospharuthenocenes and the first phospharuthenocene-phosphine.