A dihydroxo-bridged Fe(II)-Fe(III) complex: a new member of the diiron diamond core family

J Am Chem Soc. 2003 Jan 8;125(1):32-3. doi: 10.1021/ja027219t.

Abstract

The first structurally characterized Fe(II)-Fe(III) complex containing a M2(mu-OH)2 diamond core is a Robin and Day class II mixed-valence complex.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Binding Sites
  • Biomimetic Materials / chemistry
  • Crystallography, X-Ray
  • Ferric Compounds / chemistry*
  • Ferrous Compounds / chemistry*
  • Molecular Structure
  • Oxygenases / chemistry
  • Spectrometry, X-Ray Emission

Substances

  • Ferric Compounds
  • Ferrous Compounds
  • Oxygenases
  • methane monooxygenase