Giant hexagonal superstructures in diblock-copolymer membranes

Phys Rev Lett. 2002 Dec 2;89(23):238302. doi: 10.1103/PhysRevLett.89.238302. Epub 2002 Nov 18.

Abstract

We have observed polymersomes of high genus with their vesicle wall organized on the micrometer scale either in a double bilayer connected by a lattice of passages or a tubular network with hexagonal symmetry. Experimentally found shape classes are identified within a theoretical phase diagram based on the bending energy of the polymer membrane. Pronounced morphological changes could be induced and controlled by temperature.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Butadienes / chemistry*
  • Elasticity
  • Elastomers
  • Lipid Bilayers / chemistry*
  • Membranes, Artificial
  • Polyethylene Glycols / chemistry*
  • Polymers / chemistry*
  • Temperature
  • Viscosity

Substances

  • Butadienes
  • Elastomers
  • Lipid Bilayers
  • Membranes, Artificial
  • Polymers
  • Polyethylene Glycols
  • polybutadiene