Uranium complexes supported by an aryloxide functionalised triazacyclononane macrocycle: synthesis and characterisation of a six-coordinate U(III) species and insights into its reactivity

Chem Commun (Camb). 2002 Dec 7:(23):2764-5. doi: 10.1039/b208473b.

Abstract

A reactive low-valent uranium(III) complex supported by an aryloxide functionalised triazacyclononane has been synthesised and provides a platform for enhanced uranium reactivity.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Aza Compounds / chemistry
  • Electrons
  • Ligands
  • Models, Molecular
  • Molecular Structure
  • Uranium Compounds / chemical synthesis*
  • Uranium Compounds / chemistry

Substances

  • Aza Compounds
  • Ligands
  • Uranium Compounds