Abstract
Unprotected glycals reacted with trimethylsilyl cyanide in the presence of a catalytic amount of a palladium compound to yield the 2,3-unsaturated glycosyl cyanides in high yield and in alpha-selectivity.
Copyright 2002 Wiley-Liss, Inc.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Cyanides / chemistry*
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Glycosides / chemical synthesis*
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Glycosides / chemistry
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Glycosylation
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Indicators and Reagents
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Molecular Structure
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Stereoisomerism
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Trimethylsilyl Compounds / chemistry*
Substances
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Cyanides
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Glycosides
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Indicators and Reagents
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Trimethylsilyl Compounds
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trimethylsilyl cyanide