Enantioselective stereoinversion in the kinetic resolution of rac-sec-alkyl sulfate esters by hydrolysis with an alkylsulfatase from Rhodococcus ruber DSM 44541 furnishes homochiral products

Angew Chem Int Ed Engl. 2002 Nov 4;41(21):4052-4. doi: 10.1002/1521-3773(20021104)41:21<4052::AID-ANIE4052>3.0.CO;2-W.

Authors

Mateja Pogorevc¹, Wolfgang Kroutil, Sabine R Wallner, Kurt Faber

Affiliation

¹ Department of Organic and Bioorganic Chemistry, University of Graz, Heinrichstrasse 28, 8010 Graz, Austria.

PMID: 12412078
DOI: 10.1002/1521-3773(20021104)41:21<4052::AID-ANIE4052>3.0.CO;2-W

No abstract available

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Esters / chemistry*
Esters / metabolism*
Hydrolysis
Kinetics
Molecular Conformation
Rhodococcus / enzymology*
Stereoisomerism
Sulfatases / metabolism*
Sulfates / chemistry*
Sulfates / metabolism*

Substances

Esters
Sulfates
Sulfatases
alkylsulfatase