Tuning of spin density wave strengths in quasi-one-dimensional mixed-halogen-bridged nickel(III) complexes with strong electron correlation, [Ni(III)(chxn)(2)Cl(1-x)Br(x)](NO(3))(2)

Toshio Manabe; Kohei Yokoyama; Sachie Furukawa; Chihiro Kachi-Terajima; Kazuya Nakata; Fumiyasu Iwahori; Hitoshi Miyasaka; Ken-ichi Sugiura; Masahiro Yamashita; Hideo Kishida; Hiroshi Okamoto

doi:10.1021/ic025654i

Tuning of spin density wave strengths in quasi-one-dimensional mixed-halogen-bridged nickel(III) complexes with strong electron correlation, [Ni(III)(chxn)(2)Cl(1-x)Br(x)](NO(3))(2)

Inorg Chem. 2002 Oct 7;41(20):4993-5. doi: 10.1021/ic025654i.

Authors

Toshio Manabe¹, Kohei Yokoyama, Sachie Furukawa, Chihiro Kachi-Terajima, Kazuya Nakata, Fumiyasu Iwahori, Hitoshi Miyasaka, Ken-ichi Sugiura, Masahiro Yamashita, Hideo Kishida, Hiroshi Okamoto

Affiliation

¹ Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji, Tokyo 192-0397, Japan.

PMID: 12354029
DOI: 10.1021/ic025654i

Abstract

This communication describes the syntheses of the quasi-one-dimensional mixed-halogen-bridged Ni(III) complexes with strong electron correlation [Ni(chxn)(2)Cl(1-x)Br(x)](NO(3))(2) and the tuning of the spin density wave strengths of these compounds. If the Cl 3p and Br 4p make one band in the compounds, we should observe a single peak in the electronic spectra. As a result, we should observe the single peak from 1.45 to 2.00 eV depending on the mixing ratios of Cl and Br ions. Therefore, the Cl 3p and Br 4p make one band. Then, we have succeeded in tuning the spin density wave strengths of the Ni(III) complexes with the strong electron correlation by mixing the bridging halogen ions successively.