Pressure evolution of the high-frequency sound velocity in liquid water

Phys Rev Lett. 2002 Sep 16;89(12):125502. doi: 10.1103/PhysRevLett.89.125502. Epub 2002 Aug 30.

Abstract

The high-frequency sound velocity v( infinity ) of liquid water has been determined to densities of 1.37 g/cm(3) by inelastic x-ray scattering. In comparison to the hydrodynamic sound velocity v(0), the increase of v( infinity ) with density is substantially less pronounced, indicating that, at high density, the hydrogen-bond network is decreasingly relevant to the physical properties of liquid water. Furthermore, we observe an anomaly in v( infinity ) at densities around 1.12 g/cm(3), contrasting the smooth density evolution of v(0).