The first coordination compound containing three different types of spin carriers: 2p-3d-4f (TCNQ.-, Cu2+ and Gd3+)

Augustin M Madalan; Herbert W Roesky; Marius Andruh; Mathias Noltemeyer; Nicolae Stanica

doi:10.1039/b202628g

The first coordination compound containing three different types of spin carriers: 2p-3d-4f (TCNQ.-, Cu2+ and Gd3+)

Chem Commun (Camb). 2002 Aug 7:(15):1638-9. doi: 10.1039/b202628g.

Authors

Augustin M Madalan¹, Herbert W Roesky, Marius Andruh, Mathias Noltemeyer, Nicolae Stanica

Affiliation

¹ University of Bucharest, Faculty of Chemistry, Inorganic Chemistry Laboratory, Str. Dumbrava Rosie nr. 23, 70254-Bucharest, Romania.

PMID: 12170820
DOI: 10.1039/b202628g

Abstract

A novel heterospin system, [(CuL)2Gd(TCNQ)2].TCNQ-.CH3OH.2CH3CN, is obtained by reacting the mononuclear complex, [CuL], with gadolinium(III) nitrate, followed by the substitution of the nitrato ions with anionic organic radicals.