Abstract
The stereochemistries of the title compounds, both C(16)H(24)Cl(2)O, have been established by X-ray diffraction. In both structures, the seven-membered ring adopts the same conformation, whereas the six-membered ring shows an envelope conformation in the epoxydodecane structure and a boat conformation in the dodecan-9-one structure.
MeSH terms
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Bridged-Ring Compounds / chemistry*
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Crystallography, X-Ray
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Epoxy Compounds / chemistry*
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Hydrogen Bonding
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Models, Molecular
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Morocco
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Oils, Volatile / chemistry*
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Plant Oils / chemistry*
Substances
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(1,3,8,10)-2,2-dichloro-3,7,7,10-tetramethyltricyclo(6.4.0.0(1,3))dodecan-9-one
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(1,3,8,9,10)-2,2-dichloro-9,10-epoxy-3,7,7,10-tetramethyltricyclo(6.4.0.0(1,3))dodecane
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Bridged-Ring Compounds
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Epoxy Compounds
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Oils, Volatile
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Plant Oils