Revealing the photophysics of fac-[(dppz-12-NO2)Re(CO)3(4-Me2Npy)]+: a picosecond time-resolved IR study

Joanne Dyer; David C Grills; Pavel Matousek; Anthony W Parker; Michael Towrie; Julia A Weinstein; Michael W George

doi:10.1039/b200586g

Revealing the photophysics of fac-[(dppz-12-NO2)Re(CO)3(4-Me2Npy)]+: a picosecond time-resolved IR study

Chem Commun (Camb). 2002 Apr 21:(8):872-3. doi: 10.1039/b200586g.

Authors

Joanne Dyer¹, David C Grills, Pavel Matousek, Anthony W Parker, Michael Towrie, Julia A Weinstein, Michael W George

Affiliation

¹ School of Chemistry, University of Nottingham, University Park, Nottingham, UK NG7 2RD.

PMID: 12123021
DOI: 10.1039/b200586g

Abstract

The photophysics of fac-[(dppz-12-NO2)Re(CO)3(4-Me2Npy)]+ in CH3CN have been investigated using picosecond time-resolved IR (ps-TRIR) spectroscopy, to reveal the first example of a Re(I)-dppz complex with a charge separated lowest-lying excited state.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Kinetics
Molecular Conformation
Molecular Structure
Organometallic Compounds / chemistry*
Photochemistry
Physical Phenomena
Physics
Rhenium / chemistry*
Spectrophotometry, Infrared
Spectrophotometry, Ultraviolet
Spectroscopy, Fourier Transform Infrared
Time Factors

Substances

Organometallic Compounds
Rhenium