Novel catalysis of dendrimer-bound Pd(0) complexes: sterically steered allylic amination and the first application for a thermomorphic system

Tomoo Mizugaki; Makoto Murata; Masahiko Ooe; Kohki Ebitani; Kiyotomi Kaneda

doi:10.1039/b107452k

Novel catalysis of dendrimer-bound Pd(0) complexes: sterically steered allylic amination and the first application for a thermomorphic system

Chem Commun (Camb). 2002 Jan 7:(1):52-3. doi: 10.1039/b107452k.

Authors

Tomoo Mizugaki¹, Makoto Murata, Masahiko Ooe, Kohki Ebitani, Kiyotomi Kaneda

Affiliation

¹ Department of Chemical Science and Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan.

PMID: 12120306
DOI: 10.1039/b107452k

Abstract

Phosphinated dendrimer-bound Pd(0) complex catalysts show high stereoselectivity for allylic amination due to the surface congestion of dendrimers and can be easily recycled without loss of activity under thermomorphic conditions.