trans-Bis[O-2,4-di-tert-butylphenyl (4-methoxyphenyl)dithiophosphonato-kappa(2)S,S']nickel(II)

Yusuf Ozcan; Semra Ide; Mehmet Karakus; Hamza Yilmaz

doi:10.1107/s0108270102008764

trans-Bis[O-2,4-di-tert-butylphenyl (4-methoxyphenyl)dithiophosphonato-kappa(2)S,S']nickel(II)

Acta Crystallogr C. 2002 Jul;58(Pt 7):m388-9. doi: 10.1107/s0108270102008764. Epub 2002 Jun 20.

Authors

Yusuf Ozcan¹, Semra Ide, Mehmet Karakus, Hamza Yilmaz

Affiliation

¹ Department of Engineering Physics, Hacettepe University, Beytepe 06532, Ankara, Turkey.

PMID: 12094036
DOI: 10.1107/s0108270102008764

Abstract

In the the title compound, [Ni(C(21)H(28)O(2)PS(2))(2)], the Ni atom resides on an inversion centre and is coordinated in a square-planar array by four S atoms, with Ni[bond]S and P[bond]S bond lengths of 2.2336 (12)/2.2351 (13) and 1.9910 (16)/2.0010 (17) A, respectively. The two O-2,4-di-tert-butylphenyl and two 4-methoxyphenyl moieties adopt trans configurations about the central Ni atom.