Chlorobis(thiourea-kappa S)copper(I) bis(4,5-diazafluoren-9-one) monohydrate

Zhiyong Wu; Duanjun Xu; Jingyun Wu; Michael Y Chiang

doi:10.1107/s0108270102009022

Chlorobis(thiourea-kappa S)copper(I) bis(4,5-diazafluoren-9-one) monohydrate

Acta Crystallogr C. 2002 Jul;58(Pt 7):m374-6. doi: 10.1107/s0108270102009022. Epub 2002 Jun 12.

Authors

Zhiyong Wu¹, Duanjun Xu, Jingyun Wu, Michael Y Chiang

Affiliation

¹ Department of Chemistry, Zhejiang University, Hangzhou Zhejiang, People's Republic of China.

PMID: 12094031
DOI: 10.1107/s0108270102009022

Abstract

The title compound, [CuCl(CH(4)N(2)S)(2)] x 2C(11)H(6)N(2)O x H(2)O, consists of molecules of a Cu(I)-thiourea complex, free 4,5-diazafluoren-9-one (dafone) and crystalline water. The planar complex molecule has trigonal coordination geometry around the Cu(I) atom. The dafone and water molecules, which are hydrogen bonded to the Cu(I) complex, are approximately coplanar with this complex. The crystal displays a sheet structure and pi-pi stacking is observed between neighbouring sheets.