Polymer-bound 1-aryl-3-alkyltriazenes as modular ligands for catalysis. Part 1: synthesis and metal coordination

Stefan Bräse; Stefan Dahmen; Frank Lauterwasser; Nicholas E Leadbeater; Emma L Sharp

doi:10.1016/s0960-894x(02)00277-9

Polymer-bound 1-aryl-3-alkyltriazenes as modular ligands for catalysis. Part 1: synthesis and metal coordination

Bioorg Med Chem Lett. 2002 Jul 22;12(14):1845-8. doi: 10.1016/s0960-894x(02)00277-9.

Authors

Stefan Bräse¹, Stefan Dahmen, Frank Lauterwasser, Nicholas E Leadbeater, Emma L Sharp

Affiliation

¹ Kekulé-Institut für Organische Chemie und Biochemie der Rheinischen Friedrich-Wilhelms-Universität Bonn, Gerhard-Domagk-Strasse. 1, Germany. braese@uni-bonn.de

PMID: 12086831
DOI: 10.1016/s0960-894x(02)00277-9

Abstract

A range of di- and tri-substituted triazenes have been synthesized from a polymer-supported diazonium salt and various primary and secondary amines. The triazenes obtained were treated with transition metal salts to form polymer-supported metal complexes in firstly a general screen and then in a specific manner.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Amines / chemistry
Catalysis
Chemistry, Organic / methods
Combinatorial Chemistry Techniques
Diazonium Compounds / chemistry
Ligands
Organometallic Compounds / chemical synthesis
Organometallic Compounds / chemistry
Palladium / chemistry*
Polymers / chemistry*
Ruthenium / chemistry*
Triazenes / chemical synthesis
Triazenes / chemistry*

Substances

Amines
Diazonium Compounds
Ligands
Organometallic Compounds
Polymers
Triazenes
Palladium
Ruthenium