Abstract
A new chiral MeO-PEG-supported ferrocenyl oxazoline was synthesized and successfully employed in the enantioselective phenyl transfer to aldehydes. The products were obtained in high yields and with excellent enantioselectivities (up to 97% ee). Furthermore, the recovery of the ferrocene was facile, and catalyst efficiency was maintained in subsequent reactions.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Benzaldehydes / chemistry*
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Benzhydryl Compounds / chemistry*
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Catalysis
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Ferrous Compounds / chemical synthesis*
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Ferrous Compounds / chemistry
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Metallocenes
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Oxazolone / analogs & derivatives*
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Oxazolone / chemical synthesis*
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Polymers / chemistry
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Stereoisomerism
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Zinc / chemistry
Substances
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Benzaldehydes
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Benzhydryl Compounds
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Ferrous Compounds
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Metallocenes
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Polymers
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trifluoromethyloxazolinone
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Oxazolone
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Zinc
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ferrocene