A mass balance model describing multiyear fate of organochlorine compounds in a high Arctic lake

Environ Sci Technol. 2002 Mar 1;36(5):996-1003. doi: 10.1021/es010952k.

Abstract

Data collected over a 3-year study of a high arctic watershed and lake are used to understand the fate of organochlorine compounds (OCs) and form the basis of a mass balance contaminant fate model. The model uses the fugacity/aquivalence approach to describe OC dynamics between air, stream inflows and outflow, the water column, and surficial sediments. The steady-state model results indicate that stream inflows contributed from 96 to >99% of total chemical loadings, but 57-98% of total loadings were lost from the lake via the outlet, the percentage of which is controlled by the hydrologic regime of the high arctic lake. Conversely, only 0.4-3.4% of loadings were retained within the sediments due to the high export rate, minimal scavenging from the water column and low organic carbon fraction of the sediments. Using the unsteady-state model, which includes year-round processes, degradation was estimated to account for losses of 7-32% for the more persistent OCs and 42-50% for the less persistent OCs (alpha-HCH, gamma-HCH, and endosulfan I). If loadings were eliminated, water column concentrations would decline with half-lives <1 year for less persistent OCs and 1-2 years for the more persistent OCs, whereas the half-lives for OCs in sediment are 8-25 years.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Arctic Regions
  • Forecasting
  • Geologic Sediments / chemistry
  • Half-Life
  • Hydrocarbons, Chlorinated*
  • Insecticides / chemistry*
  • Models, Chemical*
  • Water Movements
  • Water Pollutants, Chemical / analysis*

Substances

  • Hydrocarbons, Chlorinated
  • Insecticides
  • Water Pollutants, Chemical