Electrochemical method at laboratory scale for the treatment of biorefractory solutions with high phenol content--1000 ppm is described. Total degradation of phenol was obtained at alkaline pH when NaCl was present using Bi-doped and pure lead dioxide electrodes. A filter press cell of 63 cm2 geometric area was used for this purpose. Measurements of chemical oxygen demand (COD), phenol, carbon monoxide, carbon dioxide, and volatile organic compounds (VOCs) have been used to characterise the electrochemical process for phenol elimination. It is worth noting that in the absence of NaCl, the charge efficiency of COD removal was independent of the current density in the range studied (50-100 mA cm(-2)) Moreover, when NaCl was present, the current efficiency for COD and phenol removal increase as the chloride concentration increases. Chloroform was the only halocompound detected at the end of reaction. For both electrodes, Bi-doped and pure lead dioxide, the chloroform concentration at the end of the electrolysis decreases, working at low current densities and for low chloride concentrations.