The observed ratio of C2H6 to C2H2 in the Jovian stratosphere increases from approximately 55 at 2 mbar to approximately 277 at 12 mbar. In current photochemical models this ratio typically increases between 2 and 12 mbar by a factor of < or = 3. Recent laboratory kinetics studies on the reaction between C2H3 and H2 to form C2H4 suggest an efficient chemical mechanism for hydrogenation of C2H2 to C2H6. Inclusion of this scheme as part of a comprehensive updated model for hydrocarbon photochemistry in the atmosphere of Jupiter provides an explanation of the altitude variation of the C2H6/C2H2 ratio. The sensitivity of these results to uncertainties in the key rate constants at low temperatures is illustrated, identifying needs for additional laboratory measurements. Since the key reaction rate constants decrease with decreasing temperature, the hydrogenation of C2H2 as proposed predicts a qualitatively decreasing trend in the C2H6/C2H2 value with decreasing distance from the Sun. The observed variation between Jupiter and Saturn is consistent with this prediction.