Resonant X ray scattering has been used to investigate charge localization on the octahedral iron atoms in magnetite below and above the Verwey temperature. We have measured the DAFS spectra of the 002 and 006 "forbidden" Bragg reflections permitted by the anisotropy of the iron anomalous scattering factor. We performed ab initio calculations which are in fair agreement with the experiment in the near edge region and demonstrate the sensitivity of the DAFS spectra to tiny structural and electronic changes. No change is observed, in the energy and azimuthal dependences, when the sample is cooled down below the Verwey temperature. Charge ordering can be definitely excluded and different charge localisation schemes discarded. Ab initio simulations, performed by using the refined crystallographic structure proposed for the room temperature phase, do not show a good agreement with the experiment in the extended region of the DAFS spectrum. This point is being investigated.