Synthesis and insertion reactions of the cyclometalated palladium-alkyl complexes Pd(CH(2)CMe(2)-o-C(6)H(4))L(2). Observation of a pentacoordinated intermediate in the insertion of SO(2)

J Cámpora; J A López; P Palma; D del Rio; E Carmona; P Valerga; C Graiff; A Tiripicchio

doi:10.1021/ic010114r

Synthesis and insertion reactions of the cyclometalated palladium-alkyl complexes Pd(CH(2)CMe(2)-o-C(6)H(4))L(2). Observation of a pentacoordinated intermediate in the insertion of SO(2)

Inorg Chem. 2001 Aug 13;40(17):4116-26. doi: 10.1021/ic010114r.

Authors

J Cámpora¹, J A López, P Palma, D del Rio, E Carmona, P Valerga, C Graiff, A Tiripicchio

Affiliation

¹ Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica, Università di Parma, Centro di Studio per la Strutturistica Diffrattometrica del CNR, Viale delle Scienze, I-43100 Parma, Italy.

PMID: 11487313
DOI: 10.1021/ic010114r

Abstract

Palladacycles of the type 2, have been synthesized by treatment of the corresponding chloroalkylcomplexes Pd(CH(2)CMe(2)C(6)H(5))ClL(2) (L(2) = (PMe(3))(2), 2a, or 1,5-cyclooctadiene (cod), 2b) with suitable bases, or by simple ligand exchange reactions from the cyclooctadiene derivative 2b. The metallacycles 2 react with activated alkynes and with sulfur dioxide, giving rise to different insertion products.