Dichloro(d-methionine-n,s)platinum(ii) at 130 k

Acta Crystallogr C. 2001 Jul;57(Pt 7):804-6. doi: 10.1107/s0108270101006874. Epub 2001 Jul 9.

Abstract

The asymmetric unit of the title compound, [PtCl2(C5H11NO2S)], a D-methionine derivative, contains two molecules with opposite chirality at the S atoms. The amino acid acts as a bidentate ligand and coordinates simultaneously through the N (amino) and S (thioether) atoms. The molecules are packed in pairs which are connected through two hydrogen bonds between the protonated carboxyl groups, with O.O distances of 2.633 (10) and 2.663 (12) A.

MeSH terms

  • Crystallography, X-Ray / methods
  • Magnetic Resonance Spectroscopy
  • Models, Molecular
  • Molecular Conformation
  • Organoplatinum Compounds / chemistry*

Substances

  • Organoplatinum Compounds
  • dicarbonylbis(octacarbonyl-mu-dicyclohexylphosphidodirhenio)platinum(II)
  • dichloro(d-methionine-n,s)platinum(II)