Legendre transform in the thermodynamics of flowing polymer solutions

Phys Rev E Stat Nonlin Soft Matter Phys. 2001 May;63(5 Pt 2):057101. doi: 10.1103/PhysRevE.63.057101. Epub 2001 Apr 11.

Abstract

We propose a Legendre transform linking two different choices of nonequilibrium variables (viscous pressure tensor and configuration tensor) in the thermodynamics of flowing polymer solutions. This may avoid some current confusions in the analysis of thermodynamic effects in polymer solutions under flow.