Mu-oxo-bis[eta5-1,2-dicarbaundecarboato)bis(N,N-dimethylacetamidinato)-tantalum] dichlooromethane hemisolvate

A E Goeta; A K Hughes; J M Malget

doi:10.1107/s010827010100436x

Mu-oxo-bis[eta5-1,2-dicarbaundecarboato)bis(N,N-dimethylacetamidinato)-tantalum] dichlooromethane hemisolvate

Acta Crystallogr C. 2001 Jun;57(Pt 6):702-3. doi: 10.1107/s010827010100436x. Epub 2001 Jun 12.

Authors

A E Goeta¹, A K Hughes, J M Malget

Affiliation

¹ Department of Chemistry, University of Durham, South Road, Durham DH1 3LE, England.

PMID: 11408676
DOI: 10.1107/s010827010100436x

Abstract

The structure of the title compound, [Ta2O(C2B9H11)2(C4H9N2)4]*0.5CH2Cl2, contains two (C2B9H11)Ta[NC(Me)NMe2]2 units bridged by a nearly linear [Ta-O-Ta 163.4 (4) degrees ] mu-oxo ligand. The dichloromethane molecule lies on a twofold axis.