7Beta-oxygenated limonoids from Trichilia elegans ssp. elegans

Phytochemistry. 2000 Dec;55(7):733-40. doi: 10.1016/s0031-9422(00)00287-9.

Abstract

Five 7beta- and 7alpha-oxygenated obacunone-type limonoids were obtained on reinvestigation of the seeds of Trichilia elegans ssp. elegans: 7-deoxo-7beta-acetoxykihadanins A and B, 7-deoxo-7beta-hydroxykihadanins A and B and 7-deoxo-7alpha-hydroxykihadanin A, the last three being isolated after acetylation procedures as their mono- and/or diacetate derivatives. This is the first report of the natural occurrence of C-7 beta-substituted limonoids without any oxygenated function at C-6. The structures of these compounds have been established on the basis of 1D- and 2D-NMR spectral techniques, ESI-mass spectrum and X-ray crystallographic data.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Flavonoids / chemistry
  • Flavonoids / isolation & purification*
  • Molecular Structure
  • Oxygen / chemistry*
  • Rosales / chemistry*
  • Spectrum Analysis

Substances

  • Flavonoids
  • Oxygen