Towards single-particle spectroscopy of small metal clusters

Phys Rev Lett. 2000 May 29;84(22):5090-3. doi: 10.1103/PhysRevLett.84.5090.

Abstract

We investigate the kinetic-energy spectra of electrons emitted from a metal cluster following laser excitation. This is done in the framework of a coupled ionic and electronic dynamics. Properly chosen laser parameters, leading to gentle excitations, yield kinetic-energy spectra which nicely resolve the multiphoton processes for each occupied state separately. This gives access to the single-particle energies in clusters, provided one works at sufficiently low temperatures and low electron flow.